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Boron clusters
Although the boron hydrides have been known to science for over a century, their complex cluster structures, such as the 12-vertex icosahedron B12H12, were elucidated decades later. It was calculated that this closed icosahedral species would need to be stabilized by a doubly negative charge. This was experimentally verified, only years later, when Hawthorne and Pitochelli isolated salts of B12H122–. Soon afterwards …
Synthetic strategies
The Department of Syntheses at the Institute of Inorganic Chemistry of the Czech Academy of Sciences has historically focused on boron cluster chemistry. We continue this legacy and strive to bring modern tools and the latest techniques to this area of chemistry. Our group focuses mainly on carboranes and metallacarboranes. The first step is always a precisely targeted cluster activation either on carbon or boron. The next step …
Boron clusters in medicinal chemistry
Probably the most famous application of BC in medicine is the Boron Neutron Capture Therapy (BNCT). This radio-therapeutic method is based on tumor-specific delivery of a drug with a high 10B nucleus content followed by a bombardment of the cells containing this drug with low-energy neutrons. Neutron bombardment results in the formation of an excited 11B* nucleus which splits into high-energy 7Li nucleus and α-particles …
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